Publications

Publications

2021

  1. Switching between XPyrano, XFurano, and AnhydroXpyranoside Synthesis (X = C, N) under Lewis acid Catalyzed Conditions” Seo, Y.; Lowe, J. M.; Romano, N.; Gagné, M. R. Org. Lett. 2021, Article ASAP. Link

2020

  1. “Modulating Electrostatic Interactions in Ion Pair Intermediates To Alter Site Selectivity in the C-O Deoxygenation of Sugars” Lowe, J. M.; Bowers, B. E.; Seo, Y.; Gagné, M. R. Angew. Chem. Int. Ed. 2020, 59, 17297-17300. Link
  2. “Spectroscopic and Computational Assessment of Silicon’s Electrophilicity in Phosphinosilylium Cations,” Riley, K. M.; Wierschen, A.L.; Lee, S. J.; Gagné, M. R. Organometallics 2020, 39, 1683-1687. Link
  3. “Silylpalladium Cations Enable the Cleavage of Nitrile C–CN Bonds,” Wierschen, A. L.; Lowe, J.; Romano, N.; Lee, S. J.; Gagné, M. R. Organometallics 2020, 39, 1258-1268. Link

2019

  1. “Selective deoxygenation of gibberellic acid with fluoroarylborane catalysts,” Seo, Y.; Gudz, A.; Lowe, J.; Gagné, M. R. Tetrahedron. 2019, 75, 130712. Link
  2. “Silylpalladium Cations Enable the Oxidative Addition of C(sp3)–O Bonds.” Wierschen, A. L.; Romano, N.; Lee, S. J.; Gagné, M. R. J. Am. Chem. Soc. 2019, 141, 16024–16032. Link
  3. “Controlling Sugar Deoxygenation Products from Biomass by Choice of Fluoroarylborane Catalyst.” Seo, Y.; Lowe, J.; Gagné, M.R. ACS Catal. 2019, 9, 6648-6652. Link
  4. “Site Selective Amide Reduction of Cyclosporine A Enables Diverse Derivation of an Important Cyclic Peptide.” Peruzzi, M.T.; Gallou, F.; Lee, S.; Gagné, M.R. Org. Lett. 2019,  21,  9,  3451-3455. Link
  5. “Harnessing the reactivity of poly(methylhydrosiloxane) for the reduction and cyclization of biomass to high-value products.” Hein, N.M.; Seo, Y.; Lee, S.; Gagné, M.R. Green Chem. 2019, 21, 2662- 2669. Link

2018 

  1. “Boron-Catalyzed Site-Selective Reduction of Carbohydrate Derivatives with Catecholborane” Lowe, J.; Seo, Y.; Gagné, M.R. ACS Catal. 2018, 8, 8192-8198. Link
  2. “Silylium (R3Si+) Catalyzed Condensative Cyclization for Anhydrosugar Synthesis” Seo,Y.;Gagné, M.R. ACS Catal. 2018, 8, 6993-6999. Link
  3. “Chemoselective amide reductions by heteroleptic fluoroaryl boron Lewis acids” Peruzzi, M. T.; Mei, Q.; Lee, S.; Gagné, M.R. Chem. Commun. 2018, 54, 5855-5858. Link.
  4. “Homogeneous catalysis for the production of low-volume, high-value chemicals from biomass” Bender, T.A.; Dabrowski, J.A.; Gagné, M.R. Nature Reviews Chemistry. 2018, 2, 35-46.Link
  5. “Computed thermodynamic stabilities of silylium Lewis base adducts” Roselli, C. A.; Gagné, M. R. Org. Biomol. Chem. 2018, 16, 2318-2323. Link
  6. “Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions” Bender, T. A.; Payne, P. R.; Gagné, M. R. Nat. Chem. 2018, 10, 85-90.Link

2017

  1. “Positional Selectivity in the Hydrosilylative Partial Deoxygenation of Disaccharides by Boron Catalysts” Seo, Y.; Gagné, M. R. ACS Catal. 2018, 8, 81–85. Link
  2. “Gold(I) Catalyzed Dearomative Claisen Rearrangement of Allyl, Allenyl Methyl, and Propargyl Aryl Ethers” Peruzzi, M. T.; Lee, S. J.; Gagné, M. R. Org. Lett. 2017, 19, 6256–6259. Link
  3. “Taming Silylium Ions for Synthesis: N-Heterocycle Synthesis via Stereoselective C–C Bond Formation” Moyer, B.; Gagné, M. Synlett 2017, 28, 2429–2434. Link
  4. “Phosphines as Silylium Ion Carriers for Controlled C−O Deoxygenation: Catalyst Speciation and Turnover Mechanisms” Gudz, A.; Payne, P. R.; Gagné, M.R. Organometallics 2017, 36, 4047-4053.  Link
  5. “Biomimetic Platinum-Promoted Polyene Polycyclizations: Influence of Alkene Substitution and Pre-cyclization Conformations” McCulley, C. H.; Geier, M. J.; Hudson, B. M.; Gagné, M. R.; Tantillo, D. J. J. Am. Chem. Soc. 2017, 139, 11158. Link

2016

  1. “Delineating The Multiple Roles of B(C6F5)3 in the Chemoselective Deoxygenation of Unsaturated Polyols” Bender, T.A.; Dabrowski, J.A.; Gagné, M. R.  ACS Catal. 20166, 8399. Link
  2. “Gold(I)-catalyzed addition of aldehydes to cyclopropylidene bearing 6-aryl-1,5 enynes” Roselli, C.A.; Gagné, M. R. Org. Biomol. Chem. 2016, 14, 11261. Link
  3. “Investigation of a Catenane with a Responsive Noncovalent Network: Mimicking Long-Range Responses in Proteins” Chung, M. K.; White, P. S.; Lee, S. J.; Gagné, M. R.; Waters, M. L. J. Am. Chem. Soc. 2016, 138, 13344. Link
  4. “Diastereoselective B(C6F5)3‑Catalyzed Reductive Carbocyclization of Unsaturated Carbohydrates” Bender, T. A.; Dabrowski, J. A.; Zhong, H.; Gagné, M. R. Org. Lett. 2016, 18, 4120. Link
  5. “Tetrameric psuedo-peptide receptors with allosteric properties” Chung, M. K.; Lee, S. J.; Waters, M. L.; Gagné, M. R. ChemCommun. 2016, 52, 8103. Link

2015

  1. “Chemoselective conversion of biologically sourced polyols into chiral synthons” Adduci, L. L.; Bender, T. A.; Dabrowski, J. A.; Gagné, M. R. Nat. Chem. 2015, 7, 576. Link
  2. “Promoting C−C Bond Coupling of Benzyne and Methyl Ligands in Electron-Deficient (triphos)Pt−CH3+ Complexes” Aseman, M. D.; Roselli, C. A.; Gagné, M. R. Organometallics 2015, 34, 2707. Link

2014

  1.  “Gold-Catalyzed Diastereoselective Cycloisomerization of Alkylidene- Cyclopropane-Bearing 1,6-Diynes” Zheng, H.; Adduci, L. L.; Felix, R. J.; Gagné, M. R. Angew. Chemie, 2014, 126, 8038.
  2.  “Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N3Pt2+ Catalysts” Nguyen, H.; Gagné, M. R. ACS Catal. 2014, 855. Link
  3. “Diastereoselective Pt Catalyzed Cycloisomerization of Polyenes to Polycycles” Geier, M. J.; Gagné, M. R. J. Am. Chem. Soc. 2014. Link
  4. “Metal-Free Deoxygenation of Carbohydrates” Adduci, L. L.; McLaughlin, M. P.; Bender, T. A.; Becker, J. J.; Gagné, M. R. Angew. Chemie Int. Ed. 2014Link

2013

  1. “Thiourea-Catalyzed Aminolysis of N-Acyl Homoserine Lactones” M. A. Bertucci, S. J. Lee, M. R. Gagné Chem. Commun. 2013, 49, 2055-2057. Link
  2. “Catalytic Enantioselective Cyclization and C3-Fluorination of Polyprenoids” N. A. Cochrane, H. Nguyen, M. S. Brookhart, M. R. Gagné, J. Am. Chem. Soc. 2013, 135, 628-631. Link
  3. “Catalytic Platinum-Catalyzed Cation-Olefin Reactions with Alkene Terminating Groups” J. G. Sokol, N. A. Cochrane, J. J. Becker, M. R. Gagné, Chem. Commun. 201348, 5046-5048. Link
  4. “Iridium-catalyzed hydrosilylative reduction of glucose to hexane(s)” M. P. McLaughlin, L. A. Adduci, J. J. Becker, M. R. Gagné, J. Am. Chem. Soc. 2013, 135, 1225-1227. Link
  5. “σ−π-diauration as an alternative binding mode for digold intermediates in gold(I) catalysis” D. Weber, M. R. Gagné, Chem. Sci. 2013, 4, 335-338. Link
  6. “An Oxidation Induced Cyclization/Oxygenation Scheme for the Conversion of Polyenes into C3- Oxygenated Polycycles” M. J. Geier, M. R. Gagné, Organometallics. 2013, 32, 380-383. Link

2012

  1. “Mechanistic Analysis of the Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible C–O Bond Formation” T. J. Brown, D. Weber, M. R. Gagné, R. A. Widenhoefer, J. Am. Chem. Soc. 2012, 134, 9134-9137.
  2. “Self-Assembled Multi-Component Catenanes: Structural Insights into an Adaptable Class of Molecular Receptors and [2]-Catenanes” M.K. Chung, P. S. White, S. J. Lee, M. L. Waters, M. R. Gagné J. Am. Chem. Soc. 2012, 134, 11415-11429.
  3. “Self-Assembled Multi-Component Catenanes: The Role of CH-π Interactions and β-Turn Conformations on Structure and Stability” M.K. Chung, S. J. Lee, M. L. Waters, M. R. Gagné J. Am. Chem. Soc. 2012, 134, 11430-11443.
  4. “A Photo-Flow Reactor for the Continuous Photoredox-Mediated Synthesis of C-Glycoamino Acids and C-Glycolids” R. S. Andrews, J. J. Becker, M. R. Gagné, Angew. Chem. Int. Ed. 2012, 51, 4140-4143.
  5. “The Role of Electronics and Counterions on Geminal Digold Formation and Reactivity as Revealed by Gold (I)-Aryl Model Complexes” D. Weber, T. D. Jones, L. L. Adduci, M. R. Gagné, Angew. Chem. Int. Ed. 2012, 51, 2452-2456.
  6. “Au-Catalyzed Enantioselective Cope Rearrangement of Alkenyl-Methylene Cyclopropanes” R. J. Felix, D. S. Weber, Osvaldo Gutierrez, D. J. Tantillo, M. R. Gagné, Nature Chem. 2012, 4, 405-409.
  7. “Electrophilic Fluorination of Cationic Pt-aryl Complexes” S. B. Zhao, R. Y. Wang, H. Nguyen, J. J. Becker, M. R. Gagné Chem. Commun. 2012, 48, 443-445.

2011

  1. “{Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ3P,P’,P”}[(Z)-8-mesitylcyclooct-4-en-1- yl]platinum(II) tetrafluoridoborate dichloromethane disolvate” S. B. Zhao, R.-U. Wang, M. R. Gagné Acta. Cryst. 2011 E67, m972.
  2. “Steric Crowding Makes Challenging Csp3–F Reductive Elimination Feasible” S.B. Zhao, J. J. Becker, M. R. Gagné, Organometallics 2011, 30, 3926-3929.
  3. “Oxidative Addition of Secondary C-X Bonds to Pd(0): A Beneficial Anomeric Acceleration” C. Munro- Leighton, L. L. Adduci, J. J. Becker, and M. R. Gagné, Organometallics, 2011, 13, 2406-2409.
  4. “Investigating the Rate of Photoreductive Glucosyl Radical Generation” R. S. Andrews, J. J. Becker, M. R. Gagné, Org. Lett. 2011, 13, 2406-2409.
  5. “Driving Catalyst Reoxidation in Wacker Cyclizations with Acetal-Based Metal-Hydride Abstractors” N. A. Cochrane, M. S. Brookhart, M. R. Gagné, Organometallics 2011, 30, 2457-2460.
  6. “Pd(0)/Au(I) RedOx Incompatibilities as Revealed by Pd-Catalyzed Homo-Coupling of Arylgold(I)- Complexes” D. Weber, M. R. Gagné Chem. Commun. 2011, 47, 5172 – 5174.
  7. “Terminating Pt-Initiated Cation-Olefin Reactions with Simple Alkenes“ J. G. Sokol, K. C. Sekhar, J. J. Becker, M. R. Gagné, Angew. Chem. Int. Ed., 2011, 50, 5658-5661.
  8. “Constitutional, Diastereo- and Enantioselective Amplification of 84-Membered Macrocyclic Hosts for (– )-Cytidine” M. K. Chung, K. Severin, S. J. Lee, M. L. Waters, M. R. Gagné, Chem. Science 2011, 2, 744-747.
  9. “Facile Synthesis of Salmochelin S1, S2, MGE, DGE and TGE” X. Yu, Y. Dai, T. Yang, J. J. Becker, M. R. Gagné, H. Gong Tetrahedron, 2011, 67, 144-151.

2010 

  1. “Visible Light-Mediated Intermolecular Addition of Glycosyl Halides to Alkenes” R. S. Andrews, J. J. Becker, M. R. Gagné, Angew. Chem., Int. Ed. 2010, 49, 7274-7276.
  2. “Dynamic Cyclic Thiodepsipeptide Libraries From Thiol-Thioester Exchange” S. Ghosh, L. A. Ingerman, A. Frye, S. J. Lee, M. R. Gagné, M. L. Waters, Org. Lett. 2010, 12, 1860-1863.

2009 and prior

  1. “A Dinuclear Gold-Silver Resting State May Explain Silver Effects in Gold(I)-Catalysis” D. Weber, M. R. Gagné, Org. Lett. 2009, 11, 4962-4965.
  2. “Hindered Ureas as Masked Isocyanates: Facile Carbamoylation of Nucleophiles under Neutral Conditions” M. Hutchby, C. E. Houlden, J. G. Ford, S. N. G. Tyler, M. R. Gagné, G. C. Lloyd-Jones, K. I. Booker-Milburn, Angew. Chem. Int. Ed. 2009, 48, 8721-8724.
  3. “Synthesis of interlocked 56-membered rings by dynamic self-templating” M. K. Chung, P. S. White, S. J. Lee, M. R. Gagné, Angew. Chem. Int. Ed. 2009, 48, 8683-8686.
  4. “Gold(I)-Catalyzed Cascade Cyclization of Allenyl Epoxides” M. A. Tarselli, J. L. Zuccarello, S. J. Lee, M. R. Gagné, Org. Lett. 2009, 11, 3490-3492.
  5. “Mechanistic Surprises in the Gold(I)-Catalyzed Intramolecular Hydroarylation of Allenes” D. Weber, M. A. Tarselli, M. R. Gagné, Angew. Chem. Int. Ed. 2009, 48, 5733-5736.
  6. “Sn-Free Ni-Catalyzed Reductive Coupling of Glycosyl Bromides with Activated Alkenes” H. Gong, R. S. Andrews, J. L. Zucarello, S. J. Lee, M. R. Gagné, Org. Lett. 2009, 11, 879-882.
  7. “Room Temperature Pd(II) Catalyzed Carbonylation of Aryl Urea Derivatives by Selective C-H Activation” C.E. Houlden, M. Hutchby, C.D. Bailey, J.G.Ford, S.N.G. Tyler, M.R. Gagné, G.C. Lloyd- Jones, K. I. Booker-Milburn, Angew. Chem. Int. Ed. 2009, 48, 1830-1833.
  8. “Oxidative Addition of Glycosylbromides to trans-Ir(PMe3)2(CO)Cl” E. M. Pelczar, P. S. White, M. R. Gagné, Organometallics 2009, 28, 663-665.
  9. “Platinum(II) Enyne Cycloisomerization Catalysis: Intermediates and Resting States” D.L. Nelson, M.R. Gagné, Organometallics 2009, 28, 950-952.
  10. “Computational Studies on the Pt(II)-Catalyzed Cycloisomerization of 1,6-dienes into Bicyclopropanes: A Mechanistic Quandary Evaluated by DFT” F. Bell, J. Holland, J. C. Green, M. R. Gagné, Organometallics 2009, 28, 2038-2039.
  11. “Gold(I)-catalyzed intermolecular hydroarylation of allenes with nucleophilic arenes: scope and limitations” M. A. Tarselli, A. Liu, M. R. Gagné, Tetrahedron 2009, 65, 1785-1789.
  12. “A Diastereoselective Ni-Catalyzed Negishi Cross-Coupling Approach to Saturated, Fully Oxygenated C-Alkyl and C-Aryl Glycosides” H. Gong, M. R. Gagné, J. Am. Chem. Soc. 2008, 130, 12177-12183.
  13. “The Effect of Gas-Phase Reactions on the Quantitation of Cyclic Hydrazone Libraries by Electrospray Ionization (ESI) Mass Spec” H. Schiltz, M.-K. Chung, S. J. Leeb and M. R. Gagné, Org. Biomol. Chem., 2008, 6, 3597-3600.
  14. “Deracemization of a Racemic Dynamic Combinatorial Library Induced by (–)-Cytidine and (–)-2- Thiocytidine” M.-K. Chung, C. M. Hebling, J. W. Jorgenson, K. Severin, S. J. Lee, M. R. Gagné J. Am. Chem. Soc. 2008, 130, 11819-11827.
  15. “Distinct Reactivity of Pd(OTs)2: the Intermolecular Pd(II)-Catalyzed 1,2-Carboamination of Dienes” C. E. Hulden, C. D. Bailey, G. J. Ford, M. R. Gagné, G. C. Lloyd-Jones and K. I. Booker-Milburn, J. Am. Chem. Soc. 2008, 130, 10066-10067.
  16. “Asymmetric Oxidative Cation-Olefin Cyclization of Poly-enes: Evidence for Reversible Cascade Cyclization” C. A. Mullen, A. N. Campbell, Angew. Chem. Int. Ed. 2008, 47, 6011-6014.
  17. “Chiral Selection in DCC” J. J. Becker, M. R. Gagné, Submitted to “Dynamic Combinatorial Chemistry in Drug Discovery, Bioorganic Chemistry, and Materials Science”, Wiley VCH, Ben Miller, Ed.
  18. “The aerobic oxidation of alcohols with a ruthenium porphyrin catalyst in organic and fluorinated solvents” V. N. Korotchenko, K. Severin, M. R. Gagné, Org. Bio. Chem. 2008, 6, 1961-1965.
  19. “Gold(I)-Catalyzed Intramolecular Hydroarylation of Allenes” M. A. Tarselli, M. R. Gagné, J. Org. Chem. 2008, 73, 2439-2441.
  20. “Reversibility Effects on the Stereoselectivity of Pt(II)-Mediated Cascade Poly-ene Cyclizations” J. A. Feducia, M. R. Gagné, J. Am. Chem. Soc. 2008, 130, 592-599.
  21. “Regioselective Oxidative Cation-Olefin Cyclization of Poly-enes: Catalyst Turnover via Hydride Abstraction” C. A. Mullen, M. R. Gagné, J. Am. Chem. Soc. 2007, 129, 11880-11881.
  22. “Gold(I)-Catalyzed Asymmetric Cycloisomerization of Ene-Allenes into Vinyl-cyclohexenes” M. A. Tarselli, A. R. Chianese, S. J. Lee, M. R. Gagné, Angew. Chem. Int. Ed. 2007, 46, 6670-6673.
  23. “Palladium-Catalyzed Cyclizations of 1,ω-Dienols: Multiple Ways to Intramolecularly Trap a Carbocation” V. N. Korotchenko, M. R. Gagné, J. Org. Chem. 2007, 72, 4877-4881.
  24. “A Room Temperature Negishi Cross-Coupling Approach to C-Alkyl Glycosides” H. Gong, R. Sinisi, M. R. Gagné, J. Am. Chem. Soc. 2007, 129, 1908-1909.
  25. “Room Temperature β-H Elimination in (P2P)Pt(OR) Cations: Convenient Synthesis of a Platinum Hydride” A. N. Campbell, M. R. Gagné, Organometallics 2007, 26, 2788-2790.
  26. “Electrophilic Activation of Alkenes by Pt(II): So Much More Than a Slow Version of Pd(II)” A. R. Chianese, S. J. Lee, M. R. Gagné, Angew. Chem. Int. Ed. 2007, 46, 4042-4059.
  27. “The Discovery of an Enantioselective Receptor for (–)-adenosine from a Racemic Dynamic Combinatorial Library” S. M. Voshell, S. J. Lee, M. R. Gagné, J. Am. Chem. Soc. 2006, 128, 12422-12423.
  28. “Density Functional Study of Platinum(II)-Mediated Bicyclization of 1,6-Dienylphenols” T. Nowroozi- Isfahani; D. G. Musaev; K. Morokuma; M. R. Gagné, Organometallics 2007, 26, 2540-2549.
  29. “Modular Catalysts for Diene Cycloisomerization: Rapid and Enantioselective Variants for Bicyclopropane Synthesis” J. A. Feducia; A. N. Campbell; M. Q. Doherty; M. R. Gagné J. Am. Chem. Soc. 2006, 128, 13290-13297.
  30. “Modulating the Activity and Selectivity of an Immobilized Ru-Porphyrin Catalyst using a Fluorous Solvent” E. Burri, S. M. Leeder, K. Severin, M. R. Gagné, Adv. Synth. & Cat. 2006, 348, 1640-1644.
  31. “Catalytic Asymmetric Prins-Cyclizations: Cation Generation and Trapping with (BINAP)Pt-dications” C. A. Mullen, M. R. Gagné, Org. Lett. 2006, 8, 665-668.
  32. “Protonation of Cationic Pt-C Bonds under Mild Conditions: A Role for Ligand torsional Effects? J. A. Feducia, J. W. Anthis, A. N. Campbell, M. R. Gagné Organometallics 2006, 25, 3114-3117.
  33. “Fluorophobic Enhanced Decontamination of a Mustard Simulant by Porous Monolithic Flow Through Columns” V. N. Korotchenko, M. R. Gagné, React. & Funct. Polym.. 2005, 67, 422-431.
  34. “Synthesis and Characterization of Bifunctional Compounds: Templates for Metal Crown-Ether Assemblies” D. L. Nelsen, P. S. White, M. R. Gagné, Organometallics 2005, 24, 5479-5483.
  35. “Rigidified Dendritic Structures for Imprinting Chiral Information” S. M. Voshell, M. R. Gagné, Organometallics 2005, 26, 6338-6350.
  36. “Cycloisomerization of Dienes with Carbophilic Lewis Acids: Mimicking Terpene Biosynthesis with Pt(II) Catalysts” W. D. Kerber, M. R. Gagné, Org. Lett. 2005, 7, 3379-3381.
  37. “Synthesis and Ligand Exchange Reactions of P2Pd(II) and P2Pt(II) Salicylaldimates” W. D. Kerber, D. L. Nelsen, P. S. White, M. R. Gagné JCS Dalton 2005, 1948-1951.
  38. “Pd(II)–Catalyzed Cyclogeneration of Carbocations: Subsequent Rearrangement and Trapping under Oxidative Conditions” J. H. Koh, C. Mascarenhas, M. R. Gagné, Tetrahedron 2004, 60, 7405-7410 (Invited)
  39. “Platinum(II)-Catalyzed 1,6-Diene Cycloisomerizations: Turnover in the Absence of -Hydride Elimination” W. D. Kerber, J. H. Koh, M. R. Gagné Org. Lett. 2004, 6, 3013-3015.
  40. “Exploiting the Synergy Between Coordination Chemistry and Molecular Imprinting in the Quest for New Catalysts” J. J. Becker, M. R. Gagné, Accts. Chem. Res. 2004, 37, 798-804.
  41. “Amino-Acid Containing Metallomonomers Copolymerized into Porous Organic Polymers: Applicability to Allylic Alkylation Catalysis” H. Aït-Haddou, S. M. Leeder, M. R. Gagné, Inorg. Chim. Acta. 2004, 357, 3854-3864 (Invited Submission for Prof. Tobin J. Marks 60th Birthday).
  42. “Persistent N-Chirality as the Only Source of Asymmetry in Non-Racemic N2PdCl2 Complexes” K. A. Pelz, P. S. White, M. R. Gagné, Organometallics 2004, 23, 3210-3217.
  43. “Pd(II)- and Pt(II)-Mediated Multicyclization Reactions of 1,5- and 1,6-Dienes. Evidence in Support of Carbocation Intermediates” J. H. Koh, M. R. Gagné Angew. Chem. Int. Ed. 2004. 43, 3459-3461.
  44. ”Crown-ether functionalised second coordination sphere palladium catalysts by molecular imprinting” F. Viton, P. S. White, M. R. Gagné, Chem. Commun. 2003, 3041-3042.
  45. “The fluorophobic Effect Promotes Partitioning of Organics into Macroporous Organic Polymers. A Method for Achieving High Local Concentrations” S. Leeder, M. R. Gagné J. Am. Chem. Soc. 2003, 125, 9048-9054.
  46. “Synthesis and Characterization of Chiral Diphosphine Platinum(II) VANOL and VAPOL Complexes” J. J. Becker, P. S. White, M. R. Gagné Organometallics 2003, 22, 3245-3249.
  47. “Ethylene-Linked bis(phenol) Ligands: Efficient Synthesis, Ti(IV) Coordination Chemistry, and Lewis Acid Catalysis” J. W. Anthis, A. O. Larsen, P. S. White, and M. R. Gagné, J. Organometal. Chem, 2003, 688, 121-124.
  48. “Imprinting Chiral Information into Rigidified Dendrimers” J. J. Becker, M. R. Gagné, Organometallics 2003, 22, 4984-4998.
  49. “The NMR Structure of an Unusual Pt2(BINOL) Dimer: More Surprises From a Seemingly Simple Chiral Ligand” N. M. Brunkan, M. R. Gagné, Organometallics 2002, 21, 4711-4717.
  50. “Electron poor benzonitriles as labile, stabilizing ligands in asymmetric catalysis” J.J. Becker, L.J. Van Orden, P.S. White, M.R. Gagné, Organic Letters 2002, 4, 727-730.
  51. “Thermodynamic and Kinetic Relationship Between Lewis Acid-Lewis Base Complexes Relevant to the P2Pt(OTf)2-Catalyzed Diels-Alder Reaction” N. M. Brunkan, P. S. White, M. R. Gagné, Organometallics 2002, 21, 1565-1575.
  52. “(dppe)Pt(OTf)2 and (R-BINAP)Pt(OTf)2 Lewis acids Catalyze the Diels-Alder Reaction by different Mechanisms” N. M. Brunkan, M. R. Gagné, Organometallics 2002, 21, 1576-1582.
  53. “Structure and Reactivity of Mixed Alkali-Metal Alkoxide/Aryloxide Catalysts” R. M. Kissling, M. R. Gagné, J. Org. Chem. 2001, 66, 9005-9010.
  54. “The Disparate Roles of Chiral Ligands and Molecularly Imprinted Cavities in Asymmetric Catalysis and Chiral Poisoning” J. H. Koh, A. O. Larsen, P.S. White, M. R. Gagné, Organometallics 2002, 21, 7-9.
  55. “Asymmetric Catalysis with the Normally Unresolvable, Conformationally Dynamic 1,1’- bis(diphenylphosphino)biphenyl (Biphep)” J. J. Becker, P. S. White, M. R. Gagné, J. Am. Chem. Soc. 2001, 123, 9476-9477.
  56. “Can a fluorous biphase solvent system improve a polymer immobilized heterogeneous hydrogenation catalyst?” S. L. Vinson, and M. R. Gagné, Chem. Commun. 2001, 1130-1131.
  57. “Pt(II)-Catalyzed Ene Reactions: Counterion Dependent Additive and Diphosphine Electronic Effects on Asymmetric Catalysis”, J. H. Koh, A. O. Larsen, and M. R. Gagné, Organic Letters 2001, 3, 1233-1236.
  58. “Improved ester interchange catalysts”, R. M. Kissling, M. R. Gagné, Org. Lett. 2000, 2, 4209-4212.
  59. “Porogen and Crosslinking Effects on the Surface Area, Pore Volume Distribution, and Morphology of Macroporous Polymers Obtained by Bulk Polymerization” B. P. Santora, M. R. Gagné, K. G. Moloy, N. S. Radu, Macromolecules 2001, 34, 658-661.
  60. “The Mechanism of Diastereomer Interconversion in Chiral BihepPtX2 Complexes” M. Tudor, J. J. Becker, P. S. White, and M. R. Gagné, Organometallics 2000, 19, 4376-4384.
  61. “Simultaneous Atom Transfer and Nitroxide Mediated Controlled Free Radical Polymerization of Styrene” M. R. Korn, M. R. Gagné, Chem. Commun. 2000, 1711-1712.
  62. “A Polymer-Supported Rhodium Catalyst Useful in Polar Protic Solvents” R. A. Taylor, B. P. Santora, M. R. Gagné, Organic Letters 2000, 2, 1781-1783.
  63. “Effect of Chiral Cavities Associated with Molecularly Imprinted Platinum Centers on the Selectivity of Ligand Exchange Reactions at Platinum” N. M. Brunkan, M. R. Gagné, J. Am. Chem. Soc. 2000, 122, 6217- 6225.
  64. “A wolf in sheep’s clothing” B. P. Santora, M. R. Gagné, Chemical Innovation 2000, August, 23-29.
  65. “Asymmetric Synthesis of Rigid C2-Symmetric Bisferrocenyl Diol and Diamine Ligands” A. O. Larsen,
  66. R. A. Taylor, P. S. White, and M. R. Gagné, Organometallics 1999, 18, 5157-5162.
  67. “Acid-Base Adducts of Catalytically Active Titanium(IV) Lewis Acids” A. O. Larsen, P. S. White, and
  68. M. R. Gagné, Inorg. Chem. 1999, 38, 4824-4828.
  69.   “A Novel Catalytic Approach to the Chemical Detoxification of P-Ester Nerve Agents” W. Y. Mills, R. M. Kissling, and M. R. Gagné, Chem. Commun. 1999, 1713-1714.
  70. “〈,⎤-Heterotelechelic Poly(∑-caprolactone) via Ring-Opening/Chain Transfer Polymerization: Expedient Route to AB and ABC Block Copolymers” M. R. Korn, J. D. Lennon, G. L. Glish, and M. R. Gagné, Macromolecules 1999, 32, 5149-5153.
  71. “Methods for the Synthesis of the Diels-Alder Catalysts (ArO)2TiX2 (X = Cl, Br, I; Ar = 2-tert-butyl-6- methyl-phenyl)” B. P. Santora, P. S. White, and M. R. Gagné, Organometallics 1999, 18, 2557-2560.
  72. “Alkali Metal Alkoxide Clusters: Convenient Catalysts for the Synthesis of Methylphosphonates” R. M. Kissling and M. R. Gagné, J. Org. Chem. 1999, 64, 1585-1590.
  73. “Synthesis and Characterization of Chiral Platinum(II) Sulfonamides: (dppe)Pt(NN) and (dppe)Pt(NO) Complexes” J. J. Becker, P. S. White, and M. R. Gagné, Inorg. Chem. 1999, 38, 798-801.
  74.  “Synthesis and Reactivity of Ti(IV)-Salen Complexes Containing Oxygen and Chloride Ligands” H. Chen, P. S. White, and M. R. Gagné, Organometallics 1998, 17, 5358-5366.
  75. “Unorthodox C,O Binding Mode of Me2BINOL in Pt(II) Complexes” N. M. Brunkan, P. S. White, and M. R. Gagné, J. Am. Chem. Soc. 1998, 120, 11002-11003.
  76. “Synthesis and Structure of Chiral Titanium(IV) Complexes Containing N-Substituted Amino Alcohols” L. T. Armistead, P. S. White, and M. R. Gagné, Organometallics 1998, 17, 4232-4239.
  77. “Molecularly Imprinted Ti-Lewis Acid Catalysts: Applications to the Diels-Alder Reaction” B. P. Santora, A. O. Larsen, and M. R. Gagné, Organometallics 1998, 17, 3138-3140.
  78. “A Depolymerization/Chain Transfer Approach to the Synthesis of Telechelic Polycarbonates” M. R. Korn, M. R. Gagné, Macromolecules 1998, 31, 4023-4026.
  79. “‘New’ Catalysts for the Ester-Metathesis Reaction: The Role of Alkali-Metal Alkoxide Clusters in Achieving Unprecedented Reaction Rates” M. G. Stanton, C. B. Allen, R. Kissling, A. L. Lincoln, and M. R. Gagné, J. Am. Chem. Soc. 1998, 120, 5981-5989.
  80. “Platinum(II) Complexes with Constructive and Destructive Interaction of Diphosphane and Binaphthol Ligands” N. M. Brunkan, P. S. White, and M. R. Gagné, Angew. Chem. Int. Ed. Engl., 1998, 37, 1579-1582.
  81. “Synthesis and Structure of Titanium(IV) Amido Complexes Containing C2-Symmetric Bissulfonamide Ligands” L. T. Armistead, M. R. Gagné, Organometallics 1998, 17, 216-220.
  82. “A Mild Protocol for the Conversion of Simple Esters to tert-Butyl Esters” M. G. Stanton, M. R. Gagné, J. Org. Chem. 1997, 62, 8240-8242.
  83. “The Remarkable Catalytic Activity of Alkali-Metal Alkoxide Clusters in the Ester Interchange Reaction” M. G. Stanton, M. R. Gagné, J. Am. Chem. Soc. 1997, 119, 5075-5076.

Patents

  1. “P-Containing Compositions and Their Use in Hydrocyanation, Isomerization and Hydroformylation Reactions” M. R. Gagné, K. G. Moloy, N. S. Radu, B. P. Santora, W. Tam, U.S. Patent # 6,660,876.
  2. “Methods of Making Telechelic Oligomers, Methods of Making Block Copolymers and Novel Block Copolymers” M. R. Gagné, M. Korn, U.S. Patent # 6,642,322.
  3. “Catalyst for Ester Metathesis” M. R. Gagné, M. Korn, U.S. Patent # 6,143,801.
  4. “Organolanthanide-Catalyzed Hydroamination of Olefins: A Method for the Catalytic Addition of N-H Bonds to C-C Double Bonds” M. R. Gagné, T. J. Marks, U.S. Patent # 5,043,453.
  5. “Organosamarium Catalysts for the Hydroamination of Olefins” T. J. Marks, M. R. Gagné, S. P. Nolan, U.S. Patent # 5,110,948.

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